MATERIAL SAFETY DATA SHEET
Date Printed: 12/01/2008
Version 1.1
I．Identification of substance
Product details:
Product Name: ALUMINUM SULFIDE, GRANULAR, 3-6 mm, 99.99%
Formula: Al2S3
Product Number: 1040
CAS# 1302-81-4
Brand Cerametek
Manufacturer/supplier Information:
Company Beijing Cerametek New Materials Co. Ltd
Address 16 Guanghua Road,
Tongzhou Industry Development Park
Beijing, China 101113
Website:
http://www.cerametek.com
Technical Phone: 86-10-61566641
Fax: 86-10-61561674
Emergency Phone: your local emergency phone number
II． Composition/Data on components:
Chemical characterization:
Description: (CAS#)
Barium sulfide (CAS# 1302-81-4): 100%
Identification number(s):
EINECS Number: 215-109-0
Synonym:
Chemical Formula: Al2S3
III． Hazards Identification
EMERGENCY OVERVIEW
Water sensitive, decompose in water. H2S release upon water.
Irritant.
Causes severe irritation.
For additional information on toxicity, please refer to X.
IV． Fire Fighting Measures
FLASH POINT N/A
AUTOIGNITION TEMP N/A
FLAMMABILITY N/A
EXTINGUISHING MEDIA
Suitable: Noncombustible. Use extinguishing media appropriate to surrounding fire conditions.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
EXPOSURE HAZARD(S)
Material: Severe irritant.
V． Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. Wear disposable coveralls and discard them after use.
METHODS FOR CLEANING UP
Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.
VI． Handling and Storage
HANDLING
User Exposure: Do not breathe dust. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Suitable: Keep tightly closed. Store in a cool dry place. Store under nitrogen.
SPECIAL REQUIREMENTS
Moisture sensitive.
VII． Exposure Controls / PPE
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath.
PERSONAL PROTECTIVE EQUIPMENT
Other: Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing. Faceshield (8-inch minimum).
GENERAL HYGIENE MEASURES
Wash thoroughly after handling. Wash contaminated clothing before reuse. Discard contaminated shoes.
XIII． Physical/Chemical Properties
Molecular Weight 150.16 AMU
pH N/A
BP/BP Range N/A
MP/MP Range N/A
Freezing Point N/A
Vapor Pressure N/A
Vapor Density N/A
Saturated Vapor Conc. N/A
SG/Density 2.02 g/cm3
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient N/A
Decomposition Temp. N/A
Flash Point N/A
Explosion Limits N/A
Flammability N/A
Autoignition Temp N/A
Refractive Index N/A
Optical Rotation N/A
Miscellaneous Data N/A
Solubility N/A
N/A = not available
IX． Stability and Reactivity
STABILITY
Conditions of Instability: Moisture.
Conditions to Avoid: Moisture.
Materials to Avoid: Strong oxidizing agents, Strong acids.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Hydrogen sulfide gas, Sulfur oxides, Aluminum oxide.
X． Toxicological Information
ROUTE OF EXPOSURE
Multiple Routes: Harmful if swallowed, inhaled, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin.
SIGNS AND SYMPTOMS OF EXPOSURE
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
Nausea, headache, and vomiting. Exposure can cause: Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting.
XI． Ecological Information
No data available.
XII． Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Bury in a landfill site approved for the disposal of chemical and hazardous wastes. Observe all federal, state, and local environmental regulations.
XIII． Transport Information
DOT
Proper Shipping Name: Water reactive solid, Flammable, n.o.s.
UN#: 3132
Class: 4.3
Packing Group: Packing Group I
Hazard Label: Class 4.3
PIH: Not PIH
IATA
Proper Shipping Name: Water reactive solid, flammable, n.o.s.
IATA UN Number: 3132
Hazard Class: 4.3
XIV - Regulatory Information
EU ADDITIONAL CLASSIFICATION
Symbol of Danger: Xi
Indication of Danger: Irritant.
S: 26-27-36/37/39
Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable
protective clothing, gloves, and eye/face protection.
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Irritant.
Safety Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection.
US Statements: Causes severe irritation.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR.
DSL: No
NDSL: Yes
XV． Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Cerametek.com shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.
